Aktivierung von C-H- und C-F-Bindungen an Rhodium-Komplexen zur Funktionalisierung fluorierter Olefine und Ether
Facts
Run time
01/2022
– 01/2026
DFG subject areas
Molecular Chemistry
Sponsors
DFG Individual Research Grant
Description
The proposal deals with the activation of C-H and C-F bonds in fluorinated olefins and ethers at the rhodium complexes Rh(R)(PEt3)3] (R = Si(OEt)3, GePh3, Bpin). Based on mechanistic studies borylation, germylation, silylation and dehydrofluorination reactions will be developed. Based on the stoichiometric model reactions, the development of catalytic processes is envisaged.
Topics
Organization entities
Faculty of Mathematics and Natural Sciences
Address
Johann von Neumann-Haus, Institutsgeb?ude, Rudower Chaussee 25, 12489 Berlin